| S/N | DIOCESE/ARCHDIOCESE | BISHOP’S NAME | POSITION | |
| I. | Bishop of Agboville, Côte d’ Ivoire | Most Rev. Alexis Touably YOULO | President | |
| II. | Bishop of Koforidua, Ghana | Most Rev. Joseph AFRIFAH- AGYEKUM | 1st Vice President | |
| III. | Bishop of Bissau, Guinea Bissau | Most Rev. José LAMPRA CA | 2nd Vice President | |
| IV. | Priest of Nnewi, Nigeria | Rev. Fr. Vitalis Anaehobi | Secretary General | |
| V. | Priest of Dédougou, Burkina | Rev. Fr. Vincent de Paul BORO | 1st Associate Secretary General | |
| VI. | Priest of Ziguinchor, Senegal | Rev. Fr. Célestin Sagna | 2nd Associate Secretary General | |
| VII. | Priest of Owerri, Nigeria | Rev. Fr. George WC Nwachukwu | Director of Communications | |