| S/N | DIOCESE/ARCHDIOCESE | BISHOP’S NAME | POSITION |
| I. | Archbishop of Jos, Nigeria | Most Rev. Ignatius. A. KAIGAMA | President |
| II. | Bishop of Bissau, Guinea Bissau | Most Rev. Jose Camnate NA BISSIGN | 1st Vice President |
| III. | Bishop of Agboville, Côte d’ Ivoire | Most Rev. Alexis Touably YOULO | 2nd Vice President |
| IV. | Archbishop of Abuja, Nigeria | John Cardinal ONAIYEKAN | President Finance Committee |
| V. | Archdiocese of Gagnoa, Côte d’Ivoire | Most Rev. Joseph AKE | Member |
| VI. | Archbishop of Accra Ghana | Most Rev. Charles PALMER-BUCKLE | Member |
| VII. | Archbishop of Lome, Togo | Most Rev. Denis AMUZUDZAKPAH | Member |
| VIII. | Bishop of Umuahia, Nigeria | Most Rev. Lucius UGORJI | Member |
| IX. | Bishop of Otukpo, Nigeria | Most Rev. Michael APOCHI | Member |
| X. | Bishop of Sokoto, Nigeria | Most Rev. Matthew KUKAH | Member |
| XI. | Diocese of Grand- Bassam, Côte d’Ivoire | Rev. Fr. Joseph Kacou AKA | Secretary General |
| XII. | Diocese of Nnewi, Nigeria | Rev. Fr. Vitalis ANAEHOBI | 1st Associate Secretary General |
| XIII. | Diocese of Mindelo, Cabo Verde | Rev. Fr. Paolo BORGES VAZ | 2nd Associate Secretary General |
